COPOLYMERIZATION OF CO<SUB>2</SUB> AND CYCLOHEXENE OXIDE USING AGING BDIE·[Zn-Al] CATALYST
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چکیده
منابع مشابه
Copolymerization of cyclohexene oxide and carbon dioxide using (salen)Co(III) complexes: synthesis and characterization of syndiotactic poly(cyclohexene carbonate).
Synthetic routes to a series of new (salen-1)CoX (salen-1 = N,N'-bis(salicylidene)-1,2-diaminoalkane; X = halide or carboxylate) species are described and the X-ray crystal structures of two (salen-1)CoX (salen- = N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexane; X = Cl, I) complexes are presented. (R,R)-(salen-)CoX (X = Cl, Br, I, OAc, pentafluorobenzoate (OBzF(5))) catalysts are...
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Enzymatic ring-opening copolymerization of lactones was carried out by using Pseudomonas f luorescens lipase in bulk. In the copolymerizaton of r-caprolactone (E-CL) and b-valerolactone at 60°C for 10 days a copolymer with molecular weight of 3.7 x 103 was obtained and its structure was found to be of random structure having both units from 13C NMR anlaysis. Effects of the feed ratio, the react...
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A series of CoIII carboxylate based upon N,N,O,O-tetradentate Schiff base ligand framework have been prepared. X-ray diffraction analysis confirms that these Schiff base CoIII carboxylate are all monomeric species with a six-coordinated central Co in their solid structures. The activities and polycarbonate selectivity of these complexes toward the copolymerization of epoxide (cyclohexene oxide ...
متن کاملAsymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide.
Asymmetric amplification in the copolymerization of cyclohexene oxide and carbon dioxide was demonstrated using chiral zinc complexes, prepared from diethylzinc, diphenyl(pyrrolidin-2-yl)methanol, and ethanol.
متن کاملCopolymerization of cyclohexene oxide with CO2 catalyzed by tridentate N-heterocyclic carbene titanium(IV) complexes.
A new class of complexes based on titanium(IV) bearing a bisanionic mer-tridentate N-heterocyclic carbene ligand were investigated for the copolymerization of cyclohexene oxide with CO2. Upon addition of [PPN]X' salts, all complexes were found to be active and highly selective toward the formation of poly(cyclohexene oxide-alt-carbon dioxide).
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ژورنال
عنوان ژورنال: Acta Polymerica Sinica
سال: 2010
ISSN: 1000-3304
DOI: 10.3724/sp.j.1105.2006.00815